GLASS

A glass revolution is underway. Spoiler alert: it bends and bounces

Humans have been making glass for 4,000 years. But now, scientists are developing techniques that will impact everything from medicine to the way we see the universe.

three individuals in silver suits stand around the table with a glowing orange furnace behind them. One technician pours out bright orange liquid glass onto the flat silver table.
Technicians in upstate New York pour a batch of molten glass at Corning’s “test kitchen.” Here, the company tries new recipes to enhance features such as strength, color, and optical clarity.

By Jay
Bennett
Photographs byChristopher Payne
January 17, 2024NATIONAL GEOGRAPHIC

On a brisk March afternoon, Kazuhiko Akiba and a colleague stood in the courtyard of the Chiba Kogaku glass factory in Japan, ready to unveil their latest creation. A forklift wheeled out a large clay pot about the size of a hot tub and set it down before them. Dressed in the company’s sky blue uniforms, the men put on safety glasses and gloves. Then each grabbed a sledgehammer, hefted it overhead, and slammed it against the outer edges of the pot. Their blows landed with solid thwacks, chipping away heavy ceramic to reveal the prized contents beneath: a hard, luminous substance that caught the afternoon sun. It glowed in pale cerulean hues, like Arctic ice.

two arms in a white lab coat and purple latex gloves bends a reflective piece of glass in a wave pattern.

A paper-thin sheet demonstrates the flexibility of Corning’s bendable glass: an innovation that allows for foldable phone screens and curved automotive displays.

multiple apearances of the same piece of glass bouncing in an arc across a black background.

A high-speed strobe captures the rebound of a thimble-size piece of glass grown in tandem with polymers. Developed at Imperial College London, “bouncy bioglass” is being tested to help regenerate cartilage.

Akiba, the factory director, stepped back in admiration. “Kirei,” he said. Beautiful. This was the latest batch of what’s known as E6, some of the world’s purest optical glass.

Located east of Tokyo and surrounded by peanut farms, Chiba Kogaku has been making glass in handmade clay pots for more than 50 years. The technique dates to the early 1800s, when Swiss lensmaker Pierre-Louis Guinand pioneered the method of using ceramic stirrers to mix molten glass. That process yielded a product devoid of bubbles and contaminants and ideal for optics. In 1965 a Japanese firm, Ohara Glass, refined the process with its own admixture to develop E6, a so-called low-expansion glass that’s now made for Ohara only at Chiba Kogaku.

A single pot, holding about 200 gallons, takes roughly four months to create. First, the clay vessel must be hand-sculpted. Then workers pour in a mix of silica, boron oxide, aluminum oxide, and other materials and heat the pot to 2700 degrees Fahrenheit. As it melts, the molten glass must be stirred periodically for more than two days before the pot is placed in a temperature-controlled chamber to cool for two weeks.

Breaking the clay pot removes the outermost layer of glass, leaving behind a pure substance that can be remelted and formed into precise shapes that remain constant even in extreme temperatures—hence, the “low expansion” part of its name. This stability is crucial when you’re trying to build glass mirrors for large telescopes.

The market for such wildly expensive instruments, the kind that let astronomers peer into the deep recesses of space, is limited. So limited that all the E6 produced in the past 42 years has been delivered to a single buyer. A huge amount—134 tons—is for a project that, if successful, will change the way we think about the universe.

a woman stands over a large piece of glass drawing circles on the surface with templates.

A Corning employee marks sections that will be cut from a “boule” of fused silica glass. The material’s purity and strength make it ideal for advanced lenses, beam splitters, and other optical devices, as well as windows for spacecraft and submarines.
a rainbow coloring of glass seen through a lens with a black circle edge with white etched numbers.

A polarizing lens illuminates a glass cylinder that will be melted to make an optical fiber the diameter of fishing line. The straight colored lines indicate the absence of flaws in the glass that could impede light pulses as they transfer data through the fiber.
a hand in a latex glove lifts a spiral piece of glass that holds a cone and spring shape.

A laser pulsing at picosecond intervals was used to cut this delicate glass spiral. High-tech tools let inventors manipulate glass in myriad new ways; its chemical structure allows almost any shape.

E6 is just one example of how glass is being reinvented to explore a range of frontiers. In fact, glass has seen more technological and industrial developments in the past half century than in the previous millennium, prompting the UN in 2022 to recognize glass as the 100 percent recyclable building block most likely to help countries reach sustainable-development goals by 2030.

Simply put, we’ve entered a new glass age, one in which scientists will use this ancient material to radically improve our lives.

At the factory, Akiba warns me not to touch the newly exposed glass because its surface is covered with tiny shards. As the sun sets, the massive chunk continues to change hues, shimmering with hints of topaz, then aquamarine and silver. Transfixed, I watch the colors transform, the otherworldly material sparkling as though golden stars were suspended within.

There’s a popular Internet meme showing the moment toddlers are fitted with their first pair of eyeglasses. In each video, a child goes from bawling or confused to looking stunned and wide-eyed as he or she for the first time can clearly see his or her parents. That’s how eight-year-old me felt as I walked through a Costco wearing my first pair of glasses. I gawked in amazement at the sharply defined store aisles, all thanks to a technology developed more than 700 years ago and used by billions of people since.

a glass vial being held upside down over multiple jets of flame while two metal edges press against it from the sides.

A vial that will hold vaccines is fired using a shatter-resistant glass specially formulated to guard against interfering with chemicals in the drug. As production of COVID vaccines ramped up, the manufacture of reliable vials became a global priority for glassmakers.

Getting eyeglasses has become such a mundane part of modern life that we’ve practically forgotten the impact the invention of optical lenses has had on civilization. But that’s true of most of the ways that glass has profoundly changed the human experience. Try imagining life without bottles and baking dishes, mirrors and windows, light bulbs and televisions. If you’re reading this story on your mobile phone, you tapped a glass touch screen and these words popped into view via data that traveled on glass fiber-optic cables.

Humans have been progressively weaving this material ever deeper into their lives since they discovered how to produce it about 4,500 years ago. While it’s unknown exactly where the first glass was created, some of the oldest glass beads and other trinkets have turned up in Mesopotamia. Historians theorize that the first glass may have been the accidental by-product of ceramic or metal production. Whatever the case, people quickly figured out how to manipulate the process, as evidenced by a Babylonian clay tablet found in present-day Iraq, which records in cuneiform one of the earliest known glass recipes. It even notes how to tint it red.

Whether ancient or modern, nearly all glass contains the same basic formula: a mixture of silica (the primary ingredient), soda ash (to lower the melting point), and limestone (to stabilize it). But part of what makes glass special is a sort of accident of nature—the result of a process interrupted. When the main ingredients are heated to about 1800 degrees Fahrenheit and then cooled, the atoms in the mixture naturally want to form a structure like the crystalline matrix in a sheet of ice or a diamond. Instead, the atoms become trapped in a random configuration yielding something between a solid and a liquid, which can be reshaped before it cools and hardens. The result is called an amorphous solid.

A researcher at Microsoft uses laser equipment to imprint data within a piece of glass as part of the company’s Project Silica initiative. Because data is stored within the glass, and not etched on the surface, it is protected from dust and abrasion. The stability of the glass provides a way for data to be stored for thousands of years.

Test data is read back from a piece of glass using a computer-controlled microscope. The reading processes does not degrade the glass, preserving the data stored inside.

The laser-imprinted data is almost transparent, allowing for hundreds of layers of data to be stored within a thin piece of glass—the equivalent of several terabytes, or enough to store about 13 years’ worth of music. When illuminated from the side, however, the imprinted data scatters blue light toward the viewer, revealing rectangles of stored information.

This disordered molecular structure is what gives glass its superpower: a chameleonlike adaptability. Since there’s no need for its atoms to lock into a specific pattern, at elevated temperatures its structure can incorporate a wide range of chemical compounds. Such additions can provide color, flexibility, greater heat resistance, and increased strength, among other desired traits.

“The compositions of glass are infinite, and you can continuously change their properties,” says Alicia Durán, a glass professor at the Spanish Research Council and past president of the International Commission on Glass, which has worked with the UN to champion the new glass age (a term Durán often uses).

But she loves glass for another reason: “The main quality of glass is that it can be produced, reproduced, born and reborn—really in the same or other applications—forever. And so this is the basis for sustainability,” she says.

For scientists, that creates an opportunity for endless experimentation, and the centuries have shown how one advancement can continue to inspire another. Case in point: On a recent day, I visited the “test kitchen” at the Engineering and Materials Processing lab at Corning, the multinational glass and ceramics company located in upstate New York. There, technicians clad in heavily insulated, heat-reflecting suits and face shields used steel pokers and tongs to remove a white-hot cup of molten glass from an industrial furnace, carefully pouring one of the thousands of new formulas they regularly experiment with here. (Claiming trade secrets, they wouldn’t tell me anything about the one I saw them working on.)

Famously, Corning teamed with Thomas Edison to improve his light bulb in 1879. Since then, the company has debuted a parade of glass firsts, from durable Pyrex labware (used to produce penicillin and distribute the first polio vaccines) to early fiber-optic lines (the backbone of the information superhighway) and ultradurable Gorilla Glass (which—usually—keeps your phone screen from shattering).

While much of what’s in development at Corning remains secret, plenty of researchers are openly sharing their next targets. Take bioactive glass: In 1969 a University of Florida professor discovered that if you swap out some silica for calcium, you’re able to create fine glass pellets or powders that bond with shattered bones, speeding up healing.

A Coca Cola-colored chunk of glass sits in a studio setting.

The Pacific Northwest National Laboratory is working on new chemical recipes to convert radioactive waste to glass at the Hanford Site in Washington State, where plutonium was first produced almost 80 years ago. This non-radioactive test sample shows what the waste looks like once it has been vitrified, or turned to glass.

That discovery has led to bioglass being reformulated as a potential treatment for infections in bones and soft tissue wounds, says Julian Jones, a materials scientist at Imperial College London who has been studying bioglass for 25 years. If effective, the idea could solve one of the most vexing issues facing medicine, as growing numbers of pathogens evolve to become resistant to antibiotics. Jones pioneered a “bouncy bioglass,” an experimental 3D-printed, rubbery, glass polymer, designed to regrow cartilage. “For older patients with arthritis,” he says, “this is kind of the holy grail of cartilage regeneration.”

For Himanshu Jain, who directs the Institute for Functional Materials and Devices at Lehigh University, glass will play a crucial role in renewable energy. It’s already a key material in solar panels and fiberglass blades for wind turbines. Why not, Jain asks, create windows that convert solar energy into electricity? He also foresees other glass breakthroughs: glass fertilizer pellets that release nutrients and glass computer chips able to process information via light instead of electrical signals.

One of the more controversial uses for glass technology comes from the Pacific Northwest National Laboratory in Washington State, where scientists say they’ve improved upon a decades-old method to immobilize radioactive material. The team’s goal is to devise a way to contain the 56 million gallons of stored nuclear waste that still exists at the Hanford Site, a plant that processed plutonium for the Manhattan Project and during the Cold War. “Our waste has virtually the whole periodic table of elements in it, and that has atoms of multiple different sizes that like to bond with different angles,” says John Vienna, the scientist who leads the research.

To solve this problem, the team came up with many kinds of glass to incorporate the different types of radioactive pollutants. The vitrified waste will outlast the radioactive half-life of most of the toxic material—although much debate continues over where to safely store it. After Vienna and I spoke, the team overseeing the vitrification process agreed to mail me a small chunk of test glass—made from nonradioactive material—to show me what the storable waste would look like.

two men in blue suits swing sledgehammers at a massive piece of glass in attempt to remote it from its concrete vessel.

Workers at Japan’s Chiba Kogaku glass factory break a clay pot to extract a 1,500-pound chunk of a highly pure glass called E6. Produced using a century-old process, the glass will eventually be shipped to scientists at the University of Arizona in Tucson.
a man in aa blue shirt holding a torch over a large unshaped for of glass as it splits down the center.

two gloved hands holding a piece of glass under a magnifier and marks it with a pen.

After the E6 glass is removed from the clay pot, a worker scores the surface with a tungsten-tipped hammer and then heats the crack with a blowtorch (left), causing thecrack to widen evenly and the slab to split. The glass is then cut into small blocks, and a polarizing lens is used to inspect each one for imperfections (above). The blocks that pass inspection are then shipped to the Richard F. Caris Mirror Lab at the University of Arizona, where they’ll be remelted and cast as mirrors for the Giant Magellan Telescope.

When the package arrived, I pulled out a smoky gray lump, about the size of a deck of cards. It wasn’t beautiful like the chunk of E6, but the thought it could help resolve a long-standing environmental disaster gave it a different allure.

Of all the next-generation glass advancements, it was one that centered on E6 that captivated me and prompted my visit to the Chiba Kogaku factory. After the clay pot was smashed to extract the chunk of E6, technicians then used blowtorches to slice it into shoebox-size blocks, which would then be packaged and shipped to a laboratory nestled beneath a football stadium in Tucson, Arizona.

There, the world’s only customer of E6, an astronomer named Roger Angel, would use it to build the biggest telescope mirrors in the world. When completed on a mountain peak in Chile’s Atacama Desert, the Giant Magellan Telescope, as it’s known, will enable scientists to observe details of the cosmos never glimpsed before.

The secret to the Giant Magellan’s ability to see more than any previous telescope is its huge mirrors—each 27.5 feet in diameter, roughly the width of a tennis court. Mirrors are the key to the optical strength of a reflecting telescope, which relies on them to gather light. So the larger the mirror, the more light it can gather from a distant object such as a star or planet.

“We chose eight meters because it’s the size of the freeway,” Angel told me, alluding to the journey on a tractor trailer that the mirrors must make from his lab to the port in Houston where they’re loaded onto ships that take them to Chile.

But astronomers have long been confounded by the challenges of casting large mirrors; the bigger they got, the heavier and more unwieldy they became. Angel solved this by using a mold based on a honeycomb, which greatly reduced the mirror’s weight while increasing its strength and rigidity. He and his colleagues also devised a way to spin the glass as it melts to give it a slightly concave shape, reducing the time needed to grind and polish it.

three individuals are seen crouching on a raised platform over a massive vat of crushed glass.

Workers at the University of Arizona hand-load 19 tons of E6 glass into a rotating furnace that will cast the final mirror for the Giant Magellan Telescope. The glass is melted over a honeycombed mold, which will give the 27.5-footwide mirror a stiff, lightweight structure. Once cast, the mirror will be slowly cooled for three months, after which it will undergo an extensive grinding and polishing process that could last a year or more.
two men in brown shirtfs cleaning the edge of a massive silver disk housed in a complex set of red painted metal structures.

Technicians clean an E6 glass mirror on the Large Binocular Telescope located on Arizona’s Mount Graham. The mirror’s aluminum coating must be reapplied every two years to maintain the reflectivity needed to capture light signals from across the universe.
a large building that iis wider on top than on bottom holds two huge silver parabolic lenses on the front side aimed in a similar direction.

The twin 27.5-foot mirrors of the Large Binocular Telescope— the world’s largest single-piece telescope mirrors—work together to study everything from celestial bodies in our solar system to distant galaxies and black holes. The Giant Magellan Telescope, now under construction in Chile’s Atacama Desert, will feature seven similar mirrors, which will provide astronomers with enough clarity to study planets orbiting other stars for signs of life.

Angel recognized in the 1980s that advancing the field of astronomy would require larger telescope mirrors that could capture more detail. If no one else was manufacturing the mirrors he needed, why not make them himself? A former student likes to tell the story about how, back then, Angel used a small kiln to fuse two Pyrex bowls together to prove the basic concept that he could melt the type of glass he’d need for big mirrors. “I take comfort from the fact that previous great scientists, including Galileo and Newton, actually made their own telescopes,” Angel says.

Last October I was invited with other members of the media to the Mirror Lab—a cavernous facility constructed on what used to be a parking lot beneath the east stands of the University of Arizona’s football stadium—to watch the “high fire” moment when the furnace would reach peak temperature to cast the Giant Magellan’s seventh and final mirror. Weeks before, a team had carefully loaded 19 tons of E6—thousands of the shoebox-size blocks—into the circular furnace, about the size of a small swimming pool.

After casting, the glass will be slowly cooled for 85 days, then ground and polished for about a year before an aluminum coating is added to make its reflective surface.

Angel, who’s 83, stood by himself, his arms behind his back. He seemed lost in thought watching the birth of his latest creation, possibly dreaming up a new challenge. Magellan is just part of a continuum of revolutionary, some might say outlandish, projects, one idea feeding the next. He has looked into building a cloud of billions of small sunshades that would be launched into space to reduce global warming. He’s interested in developing flexible mirrors that could concentrate sunlight to produce the high heat needed to make cement, thus reducing the carbon footprint of the world’s most popular building material. He’s also investigating ways to build an observatory on the moon’s south pole.

These ventures, however, take a back seat to the Giant Magellan Telescope. When astronomers finally begin using it to survey the heavens—expected sometime around 2029—the mirrors will be able to measure distant planets passing in front of stars to a degree never before achieved, allowing scientists to determine their temperatures and whether they contain gases like methane and oxygen, possible signs of life. “It would be the discovery of the century,” Angel says.

I could hear the whirring as the furnace spun. I imagined the E6 inside, melting into a huge mirror that would make such a discovery possible. It felt like I was witnessing something historic, something that could change everything.

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I would like to think of myself as a full time traveler. I have been retired since 2006 and in that time have traveled every winter for four to seven months. The months that I am "home", are often also spent on the road, hiking or kayaking. I hope to present a website that describes my travel along with my hiking and sea kayaking experiences.
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